Material Safety Data Sheet
1. Chemical Product and Company Identification
DESCRIPTION: SUPERGLUE
PRODUCT TYPE: CYANOACRYLATE ADHESIVE
APPLICATION: KG-824; KG-852
- Manufacturer/Supplier Information
MSDS Prepared by: Elmer's Products, Inc.
1000 Kingsmill Parkway
Columbus, OH 43229
Emergency Phone Number
Poison Control Center
1-800-228-5635 ext 22
2. Composition, Information on Ingredients
The ingredients listed below have been associated with one or
more immediate and/or delayed(*) health
hazards. Risk of damage and effects depends
upon duration and level of exposure. BEFORE USING, HANDLING,
OR EXPOSURE TO THESE INGREDIENTS, READ
AND UNDERSTAND THE MSDS.
% by weight 7085-85-0 Ethyl 2-Cyanoacrylate
3. Hazards Identification
3.1 Emergency Overview
Appearance Colorless liquid Odor
Irritating CAUTION! COMBUSTIBLE
May be harmful if inhaled. Bonds
skin instantly. Causes irritation. Eye
irritant.
- HMIS Rating
HEALTH = 2 (moderate)
FLAMMABILITY = 2 (moderate)
REACTIVITY = 1 (slight)
3.2 Potential Health Effects
- Immediate Hazards
INGESTION: No hazards known to Borden.
INHALATION: May be harmful if inhaled. Liquid or vapor may cause irritation of nose, throat and lungs.
SKIN: Bonds skin instantly. Causes irritation.
EYES: Bonds eyelids instantly. Causes irritation.
- Delayed Hazards
None of the components present in this product
at concentrations equal to or greater
than 0.1% have been listed by NTP, classified by IARC, nor
regulated by OSHA as a carcinogen.
4. First Aid Measures
INGESTION: If accidently swallowed, dilute by drinking large quantities
of water. Immediately contact poison control center
or hospital emergency room for any other additional
treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing, give
artificial respiration, preferably mouth-to-mouth. Call
a physician. SKIN: If skin bonding occurs,
soak in nail polish remover or acetone
and carefully peel or roll skin apart (do not pull).
EYES: If eye contact occurs, hold eyelid open and rinse thoroughly
but gently with only water for 15 minutes and GET
MEDICAL ATTENTION. Do not use any solvents to flush
the eye and its surroundings. Liquid glue will sting
eye temporarily. Solidified glue may irritate eye like
a grain of sand and should be treated by an eye doctor.
5. Fire Fighting Measures
Autoignition Temperature 485 deg C Upper/Lower
Flammable Limits Not available Up/Lower
Explosive Limits, % by Vol Not available Flash
Point 83 deg C (CC) COMBUSTIBLE. Keep
away from heat and flame. In case of fire,
use water spray, dry chemical, foam or CO2. Use water
to keep fire-exposed containers cool.
6. Accidental Release Measures
Eliminate all ignition sources. Soak up with
absorbent material and remove to a chemical
disposal area. Prevent entry into natural bodies of
water.
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene
and safety practices. These practices
include avoiding unnecessary exposure and removal
of the material from eyes, skin and clothing. Wash
thoroughly after handling. INHALATION:
Avoid breathing vapor. Use with adequate ventilation.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
7.2 Storage
Keep away from amines. Store
in cool, dry area away from sun and heat. Keep
containers tightly closed. Exposure to
small amounts of moisture, even moisture in air, causes polymerization
and renders the product unusable. Keep
away from heat, sparks, flame and other ignition sources.
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure
control techniques may be used to effectively
minimize employee exposure: local exhaust ventilation,
enclosed system design, process isolation and remote control
in combination with appropriate use of personal protective equipment
and prudent work practices. These techniques may not necessarily
address all issues pertaining to your operations. We, therefore,
recommend that you consult with experts of your choice to determine
whether or not your programs are adequate. If
airborne contaminants are generated when the material is heated
or handled, sufficient ventilation in
volume and air flow patterns should be
provided to keep air contaminant concentration levels below
acceptable criteria.
8.2 Personal Protection
Use goggles if contact is likely. Wear impervious
gloves as required to prevent skin contact.
8.3 Exposure Guidelines
Ethyl 2-Cyanoacrylate 7085-85-0 ACGIH
TLV: 0.2 ppm (1 mg/m³) TWA OSHA PEL:
NONE ESTABLISHED
9. Physical and Chemical Properties
Percent Volatiles Not determined pH
@ 25 C Not available Specific Gravity
1.05 Appearance Colorless liquid Autoignition
Temperature 485 deg C Boiling Point 62
deg C (5 mm Hg) Vapor Density (Air=1)
> 1 Vapor Pressure, mm Hg @ 20 C 0.13
Evaporation Rate (Butyl Acetate=1) <
1 Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol Not
available Flash Point 83 deg C (CC) Freezing
Point < -20 deg C Odor Irritating Odor
Threshold, ppm Not available Solubility
in Water Negligible Coefficient of Water/Oil
Distrib. Not applicable
10. Stability and Reactivity
Normally stable, but may become unstable at high
temperatures or may react with water.
- Conditions to Avoid:
Exposure to heat, flame and incompatibles.
- Incompatibilities:
Water, alcohols, amines, bases and direct UV.
- Decomposition products may include:
Oxides of carbon.
- Hazardous polymerization:
Will not occur.
- Other Hazards:
None known to Borden.
11. Toxicological Information
See Section 3 Hazards Identification information.
Ethyl 2-Cyanoacrylate 7085-85-0 LC50:
Not available LD50: Not available
12. Ecological Information
Not determined.
13. Disposal Considerations
Recover free liquid. Absorb residue and dispose
of according to local, state/provincial,
and federal requirements. Empty container:
May contain explosive vapors. DO NOT cut, puncture or
weld on or nearby.
14. Transport Information
14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information
only and may not be specific to your package
size. You will need to apply the appropriate
regulations to properly classify your shipment for transportation.
Non-Regulated.
14.2 Canadian Transportation of Dangerous Goods (TDG)
Non-Regulated.
15. Regulatory Information (Selected Regulations)
15.1 U.S. Federal Regulations
- OSHA Hazard Communication Standard 29CFR1910.1200
This material is a "health hazard"
and/or a "physical hazard" as determined
when reviewed according to the requirements of the Occupational
Safety and Health Administration 29 CFR Part 1910.1200 "Hazard
Communication" Standard.
- SARA Title III: Section 311/312
Fire hazard Immediate health hazard
- SARA Title III Section 313 and 40 CFR Part 372
This product contains the following toxic chemical(s)
subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986, and Subpart C-Supplier Notification
Requirement of 40 CFR Part 372. None required
per SARA TITLE III SECTION 313.
- TSCA Section 8(b) Inventory
All reportable chemical substances are listed
on the TSCA Inventory. We rely on certifications
of compliance from our suppliers for chemical
substances not manufactured by Borden.
15.2 Canadian Regulations
- Workplace Hazardous Materials Information System (WHMIS)
This product has been classified in accordance
with the hazard criteria of the Controlled
Products Regulation (CPR) and the MSDS contains
all the information required by the CPR. CLASS
D, DIV 2B CLASS B, DIV 3
- Canadian Environmental Protection Act (CEPA)
All reportable chemical substances are listed
on the Domestic Substances List (DSL)
or otherwise comply with CEPA new substance notification
requirements.
- National Pollutant Release Inventory (NPRI)
This product contains the following chemical(s)
subject to the reporting requirements
of the Canadian Environmental Protection Act (CEPA)
subsection 16(1), National Pollutant Release Inventory. None
required.
16. Other Information
HL (Cautions Required): Products bearing the
HL Health Label (Cautions Required) Seal
of The Art & Creative Materials Institute, Inc.
(ACMI) are certified to be properly labeled in a program of
toxicological evaluation by a medical
expert. This program is reviewed by ACMI's
Toxicological Advisory Board. These products are certified
by ACMI to be labeled in accordance with the chronic hazard
labeling standard, ASTM D-4236 and Federal
Law, P.L. 100-695.
- User's Responsibility
The OSHA Hazard Communication Standard 29CFR
1910.1200 and the Workplace Hazardous
Materials Information System (WHMIS) require that the information
contained on these sheets be made available
to your workers. Educate and train your
workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly.
Consult with appropriate experts to guard
against hazards associated with use of this product and its
ingredients.
- Disclaimer
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT
OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE,
except that the product shall conform to contracted specifications,
and that the product does not infringe any valid United States
or Canadian patent. No claim of any kind shall be greater
in amount than the purchase price of the quantity of product
in respect of which damages are claimed. In no event shall
Seller be liable for incidental or consequential damages,
whether Buyer's claim is based on contract, breach of warranty,
negligence or otherwise.
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